Acetic acid promoted metal-free aerobic carbon-carbon bond forming reactions at α-position of tertiary amines

研究成果: Article

83 引用 (Scopus)

抜粋

The oxidative functionalization of the benzylic C-H bonds in tetrahydroisoquinolines and tetrahydro-β-carboline derivatives was investigated. C-C bond forming reactions proceeded with a range of nucleophiles (nitroalkane, enol silyl ether, indole, allylstannane, and tetrabutylammonium cyanide) under metal-free conditions and an oxygen atmosphere. Acetic acid caused a significant acceleration effect.

元の言語English
ページ(範囲)4194-4197
ページ数4
ジャーナルOrganic letters
16
発行部数16
DOI
出版物ステータスPublished - 2014 8 15

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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