A 1H NMR study on the electronic state of a chloride-bridged tetrakis(acetamidato)dirhodium complex

Miho Yamauchi, Yasuaki Takazaki, Zhiyong Yang, Takashi Kawamura, Ryuichi Ikeda

研究成果: Article査読

抄録

A temperature dependence of 1H NMR spin-lattice relaxation time in a zig-zag chain of chloride-bridged tetrakis(acetamidato)dirhodium was measured. The observed 1H relaxation was well explained by the fluctuation of the magnetic dipolar interaction between proton and paramagnetic electron spins, where each unpaired spin is coupled by the one-dimensional antiferromagnetic interaction above 35 K. The slight change of the electronic state in the Rh dimer was observed below 35 K.

本文言語English
ページ(範囲)110-111
ページ数2
ジャーナルChemistry Letters
33
2
DOI
出版ステータスPublished - 2004 2月 5
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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