A series of Ni(II) pyridyloximato (pao-) compounds [Ni(pao)2(L)2] (L = unidentate ligand): As a coordination donor building block in the assembly with Mn(III) salen analogues

H. Miyasaka, K. Mizushima, K. Sugiura, M. Yamashita

研究成果: Conference article査読

16 被引用数 (Scopus)

抄録

A series of mononuclear Ni(II) compounds [Ni(pao)2(L)2] (pao- = 2-pyridyloximate, L = pyridine (1), 4-picoline (2), 4-ethylpyridine (3), 4-tert-butylpyridine (4), and N-methylimidazole (5)) were synthesized and characterized. The structures of 1 - 3 were determined by X-ray crystallography and revealed that all compounds have the same structural motif with trans coordination fashion for the identical ligands. For magnetic data, the best-fitting to an S = 1 ground state with the zero-field splitting effect found to have the zero-field splitting parameter |D| of 3 - 4 K in this series. These compounds are good coordination donor building blocks for assembly with Mn(III) salen analogues as coordination acceptor building blocks to form 1-D magnetic chains.

本文言語English
ページ(範囲)1245-1246
ページ数2
ジャーナルSynthetic Metals
137
1-3
DOI
出版ステータスPublished - 2003 4 4
外部発表はい
イベントICSM 2002 - Shanghai, China
継続期間: 2002 6 292002 7 5

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • 材料力学
  • 機械工学
  • 金属および合金
  • 材料化学

フィンガープリント

「A series of Ni(II) pyridyloximato (pao<sup>-</sup>) compounds [Ni(pao)<sub>2</sub>(L)<sub>2</sub>] (L = unidentate ligand): As a coordination donor building block in the assembly with Mn(III) salen analogues」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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