A Pt(0) complex with cyclic (alkyl)(amino)silylene and 1,3-divinyl-1,1,3,3-tetramethyldisiloxane ligands: Synthesis, molecular structure, and catalytic hydrosilylation activity

Tomohiro Iimura, Naohiko Akasaka, Tomoyuki Kosai, Takeaki Iwamoto

研究成果: Article査読

21 被引用数 (Scopus)

抄録

A platinum(0) complex bearing a cyclic (alkyl)(amino)silylene and a 1,3-divinyl-1,1,3,3-tetramethyldisiloxane (DVTMS) was synthesized and isolated in the form of colorless crystals. The single-crystal X-ray diffraction analysis of this complex in combination with theoretical calculations indicated that the Pt→Si π-back-donation in this complex is weaker than that in the corresponding cyclic-dialkylsilylene-ligated Pt complex. The performance of this complex in the catalytic hydrosilylation of (Me3SiO)2MeSi-H with various terminal alkenes that contain functional groups was comparable to that of the corresponding cyclic dialkylsilylene/DVTMS Pt(0) complex.

本文言語English
ページ(範囲)8868-8874
ページ数7
ジャーナルDalton Transactions
46
27
DOI
出版ステータスPublished - 2017 1 1

ASJC Scopus subject areas

  • Inorganic Chemistry

フィンガープリント 「A Pt(0) complex with cyclic (alkyl)(amino)silylene and 1,3-divinyl-1,1,3,3-tetramethyldisiloxane ligands: Synthesis, molecular structure, and catalytic hydrosilylation activity」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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