A novel synthesis of (−)-callicarpenal

Daichi Oguro, Naoki Mori, Hirosato Takikawa, Hidenori Watanabe

研究成果: Article査読

3 被引用数 (Scopus)

抄録

Callicarpenal, isolated from the leaves of American beautyberry (Callicarpa americana) and Japanese beautyberry (Callicarpa japonica), exhibits significant mosquito bite-deterring activity and repellent activity against ticks and fire ants. The mosquito bite-deterring activity level of callicarpenal was reported to be similar to that of N,N-diethyl-m-toluamide. The novel synthesis of (−)-callicarpenal reported herein was accomplished by starting from (+)-pulegone. In our original approach, a novel Prins-type cyclization based on Meyer–Schuster rearrangement was featured as a key step.

本文言語English
ページ(範囲)5745-5751
ページ数7
ジャーナルTetrahedron
74
39
DOI
出版ステータスPublished - 2018 9月 27
外部発表はい

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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