A novel seven-coordinate technetium(IV) complex: Synthesis and characterization of [TcO(tpen)]2+ (tpen = N,N,N′,N′- tetrakis(2-pyridylmethyl)ethylenediamine)

Takashi Yoshimura, Masanori Kawai, Tsutomu Takayama, Tsutomu Sekine, Hiroshi Kudo, Atsushi Shinohara

研究成果: Article査読

抄録

The 1:1 reaction of [TcOCl4]- with tpen (tpen = N,N,N′,N′-tetrakis(2-pyridylmethyl)ethylenediamine) led to the formation of [TcO(tpen)]2+ which is the first example both of seven-coordinate technetium(IV) and oxotechnetium(IV). The coordination geometry of the Tc(IV) ion is a monocapped trigonal prism.

本文言語English
ページ(範囲)1624-1625
ページ数2
ジャーナルChemistry Letters
34
12
DOI
出版ステータスPublished - 2005 12 5

ASJC Scopus subject areas

  • 化学 (全般)

フィンガープリント

「A novel seven-coordinate technetium(IV) complex: Synthesis and characterization of [TcO(tpen)]<sup>2+</sup> (tpen = N,N,N′,N′- tetrakis(2-pyridylmethyl)ethylenediamine)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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