A new high-pressure and high-temperature polymorph of FeS

Hiroaki Ohfuji, Nagayoshi Sata, Hisao Kobayashi, Yasuo Ohishi, Kei Hirose, Tetsuo Irifune

研究成果: Article査読

13 被引用数 (Scopus)

抄録

A new polymorph of FeS has been observed at pressures above 30 GPa at 1,300 K by in situ synchrotron X-ray diffraction measurements in a laser-heated diamond anvil cell. It is stable up to, at least, 170 GPa at 1,300 K. The new phase (here called FeS VI) has an orthorhombic unit cell with lattice parameters a = 4.8322 (17) Å b = 3.0321 (6) Å and c = 5.0209 (8) Å at 85 GPa and 300 K. Its topological framework is based on the NiAs-type structure as is the case for the other reported polymorphs (FeS I-V). The unit cell of FeS VI is, however, more distorted (contracted) along the [010] direction of the original NiAs-type cell. For example, the c b axial ratio is ∼1.66 at 85GPa and 300 K, which is considerably smaller than that of orthorhombic FeS II (∼1.72) and NiAs-type hexagonal FeS V (=√3 ≈ 1.73). The phase boundary between FeS IV and VI is expected to be located around 30 GPa at 1,300 K. The phase transition is accompanied by gradual and continuous changes in volume and axial ratios and may be second order. At room temperature, FeS VI becomes stable over FeS III at pressures above 36 GPa. It is, therefore, suggested that the phase boundary of FeS III-VI and/or FeS IV-VI has negative pressure dependence.

本文言語English
ページ(範囲)335-343
ページ数9
ジャーナルPhysics and Chemistry of Minerals
34
5
DOI
出版ステータスPublished - 2007 7
外部発表はい

ASJC Scopus subject areas

  • 材料科学(全般)
  • 地球化学および岩石学

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