A light-induced phase exhibiting slow magnetic relaxation in a cyanide-bridged [Fe 4Co 2] complex

Masayuki Nihei; Yuki Okamoto; Yoshihiro Sekine; Norihisa Hoshino; Takuya Shiga; Isiah Po Chun Liu; Hiroki Oshio

doi:10.1002/anie.201202225

A light-induced phase exhibiting slow magnetic relaxation in a cyanide-bridged [Fe ₄Co ₂] complex

Masayuki Nihei, Yuki Okamoto, Yoshihiro Sekine, Norihisa Hoshino, Takuya Shiga, Isiah Po Chun Liu, Hiroki Oshio

金属材料研究所・物質創製研究部

研究成果: Article › 査読

114 被引用数 (Scopus)

抄録

Single-molecule magnets: A cyanide-bridged hexanuclear complex showed a thermal electron-transfer-coupled spin transition centered at 220a K. Light irradiation at low temperature (LT; HT=high temperature) generated a metastable state showing slow magnetic relaxation in measurements of the alternating-current magnetic susceptibility (Ï _m; see picture).

本文言語	English
ページ（範囲）	6361-6364
ページ数	4
ジャーナル	Angewandte Chemie - International Edition
巻	51
号	26
DOI	https://doi.org/10.1002/anie.201202225
出版ステータス	Published - 2012 6月 25

ASJC Scopus subject areas

触媒
化学 (全般)

文献へのアクセス

10.1002/anie.201202225

他のファイルとリンク

引用スタイル

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AU - Shiga, Takuya

AU - Liu, Isiah Po Chun

AU - Oshio, Hiroki

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KW - heterometallic complexes

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KW - mixed-valent compounds

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