A high-voltage and high-capacity Ti3C2Tx/BiCuS2.5 heterostructure to boost up the energy density and recyclability of zinc-ion-hybrid capacitors

Yahui Li, Weiwei Zhang, Xiaoyan Yang, Jianfeng Zhang, Zhongchang Wang, Hongmin Zhu

研究成果: Article査読

抄録

In this paper, a brand-new amorphous Ti3C2Tx/BiCuS2.5 electrode material was first invented by a facile in-situ deposition strategy, whose workable voltage window was enlarged up to 2.0 V (−1.4 V~0.6 V) with an improved capacity to 840 C g−1 at 1 A g−1 due to a “baton relay” mechanism. When the Ti3C2Tx/BiCuS2.5 electrode material was assembled for an aqueous symmetrical supercapacitor, the device exhibited a maximum energy density of 56.1 Wh kg−1 at a power density of 15.3 kW kg−1. After 10,000 cycles, the energy density was even elevated to 63.325 Wh kg−1. When the Ti3C2Tx/BiCuS2.5 material was used for a zinc-ion capacitor cathode, the device exhibited an energy density of 298.4 Wh kg−1 at a power density of 7200 W kg−1. The energy density retention of 95% after 7000 cycles and 82% after 10000 cycles clearly proved the good recyclability of Ti3C2Tx/BiCuS2.5 electrode. Based on the attentive DFT simulation and XPS analysis, the energy storage mechanism was ascribed to the co-existence of intercalation and redox battery-type capacity. This work opens a new direction with new electrode materials workable at a high voltage range for the construction of high specific energy supercapacitors.

本文言語English
論文番号106136
ジャーナルNano Energy
87
DOI
出版ステータスPublished - 2021 9

ASJC Scopus subject areas

  • 再生可能エネルギー、持続可能性、環境
  • 材料科学(全般)
  • 電子工学および電気工学

フィンガープリント

「A high-voltage and high-capacity Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>/BiCuS<sub>2.5</sub> heterostructure to boost up the energy density and recyclability of zinc-ion-hybrid capacitors」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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