A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: Syntheses and crystal structures

Suyun Zhang, Wenqian Chen, Bin Hu, Yanmei Chen, Lina Zheng, Yahong Li, Wu Li

研究成果: Article査読

12 被引用数 (Scopus)

抄録

A tetranuclear cubane-like cluster [Ni4(HL)4(DMSO) 2]·2DMSO·H2O (1) and a dinuclear compound [Cu2Cl2(H2L)2]·1.5MeOH (2) (H3L=3-(2-hydroxy-benzylideneamino)propane-1,2-diol) have been prepared and characterized by X-ray single crystal diffraction, IR, and elemental analysis. The X-ray diffraction analysis indicated that the four metals of 1 showed a Ni4O4 cubane arrangement, and two of the six faces of the Ni4O4 cubane were capped by DMSO. Complex 1 is the first reported DMSO capped Ni4O4 cubane cluster. Complex 2 contains a u2-Cl bridged dinuclear core with each CuII ion exhibiting pseudo square pyramidal geometry.

本文言語English
ページ(範囲)4147-4155
ページ数9
ジャーナルJournal of Coordination Chemistry
65
23
DOI
出版ステータスPublished - 2012

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 材料化学

フィンガープリント

「A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: Syntheses and crystal structures」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル