A convenient synthesis of (2s,3r,6s,7z)- and (2r,3s,6s,7z)-2,3-epoxy- 7,10-bisaboladiene, the sex pheromones of the southern green stink bug (nezara viridula)

Shigefumi Kuwahara, Daisuke Itoh, Walter Soares Leal, Osamu Kodama

研究成果: Article査読

6 被引用数 (Scopus)

抄録

(2S,3R,6S,7Z)-2,3-Epoxy-7,10-bisaboladiene, a sex pheromone component of the southern green stink bug, Nezara viridula (L.) was synthesized stereoselectively in four steps (19% overall yield) from (S)-4-methyl-3- cyclohexene-1-carboxylic acid. This epoxy bisaboladiene was converted in three more steps (64% yield) to its (2R,3S,6S,7Z)-isomer, another sex pheromone component of the southern green stink bug, by inverting the configuration of the epoxide ring.

本文言語English
ページ(範囲)11421-11430
ページ数10
ジャーナルTetrahedron
54
38
DOI
出版ステータスPublished - 1998 9月 17
外部発表はい

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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「A convenient synthesis of (2s,3r,6s,7z)- and (2r,3s,6s,7z)-2,3-epoxy- 7,10-bisaboladiene, the sex pheromones of the southern green stink bug (nezara viridula)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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