A Bottom-up Synthesis of Antiaromatic Expanded Phthalocyanines: Pentabenzotriazasmaragdyrins, i.e. Norcorroles of Superphthalocyanines

Taniyuki Furuyama, Takehito Sato, Nagao Kobayashi

研究成果: Article査読

38 被引用数 (Scopus)

抄録

The first example of an antiaromatic expanded phthalocyanine, classified as a norcorrole of a superphthalocyanine has been prepared and fully characterized. The newly developed phthalonitrile dimerization reaction was a crucial step, which allowed for the bottom-up synthesis of expanded phthalocyanines. Their structure was confirmed by single crystal X-ray diffraction analysis. The 20 π antiaromaticity of the macrocycles was suggested by optical and theoretical calculations.

本文言語English
ページ(範囲)13788-13791
ページ数4
ジャーナルJournal of the American Chemical Society
137
43
DOI
出版ステータスPublished - 2015 11月 4
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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