3-methyl-4-oxa-5-azahomoadamantane: Alkoxyamine-type organocatalyst for alcohol oxidation

Yusuke Sasano, Keiichi Murakami, Tomohiro Nishiyama, Eunsang Kwon, Yoshiharu Iwabuchi

研究成果: Article査読

9 被引用数 (Scopus)

抄録

Strong, silent type: A novel alkoxyamine-type organocatalyst has been discovered for alcohol oxidation (see scheme). The alkoxyamine exhibits a high catalytic activity for the oxidation of alcohols to afford the corresponding carbonyl compounds in high yield by oxidative transformation into an oxoammonium ion, which is proposed to serve as an active species.

本文言語English
ページ(範囲)12624-12627
ページ数4
ジャーナルAngewandte Chemie - International Edition
52
48
DOI
出版ステータスPublished - 2013 11 25

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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