Zirconium isotope separation by means of cation-exchange chromatography

Kazumi Kogure, Masato Kakihana, Masao Nomura, Makoto Okamoto

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The separation of zirconium isotopes has been studied by means of cation-exchange chromatography using zirconium-triammonium citrate and zirconium-diammonium citrate systems. Small but appreciable isotope fractionations were observed in both systems. In the former system, the lighest isotope 90Zr was enriched at the rear part of the zirconium band, while in the latter case 90Zr was depleted at the rear part. The elemental separation coefficients, ε, were around 1 · 10-6 for the zirconium-triammonium citrate systems and around -0,5 · 10-6 for the zirconium-diammonium citrate systems. The isotope effect is discussed in terms of the hydrolysis of the zirconium species.

Original languageEnglish
Pages (from-to)195-206
Number of pages12
JournalJournal of Chromatography A
Volume325
Issue numberC
DOIs
Publication statusPublished - 1985 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

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