XPS and BIS spectra of U3T3X4(T=Ni, Cu and X=Sn, Sb)

Takeo Ejima; Yuji Kudo; Shoji Suzuki; Takashi Takahashi; Shigeru Sato; Tadao Kasuya; Toshiro Takabatake; Takehiko Ishii

doi:10.1016/0921-4526(93)90502-W

XPS and BIS spectra of U₃T₃X₄(T=Ni, Cu and X=Sn, Sb)

Takeo Ejima, Yuji Kudo, Shoji Suzuki, Takashi Takahashi, Shigeru Sato, Tadao Kasuya, Toshiro Takabatake, Takehiko Ishii

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Valence state and U 4f core spectra of ternary uranium compounds U₃T₃X₄(T=Ni, Cu and X=Sn, Sb) are measured by X-ray photoemission and bremsstrahlung isochromat spectroscopy. The diffreences in the spectral shapes of valence bands suggest the importance of the hybridization of U 5f states with T 3d and X 5p states. For all compounds, the unoccupied U 5f state spectra are similar in shape except for small differences in the tailings.

Original language	English
Pages (from-to)	86-88
Number of pages	3
Journal	Physica B: Physics of Condensed Matter
Volume	186-188
Issue number	C
DOIs	https://doi.org/10.1016/0921-4526(93)90502-W
Publication status	Published - 1993 May 2

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Electrical and Electronic Engineering

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title = "XPS and BIS spectra of U3T3X4(T=Ni, Cu and X=Sn, Sb)",

abstract = "Valence state and U 4f core spectra of ternary uranium compounds U3T3X4(T=Ni, Cu and X=Sn, Sb) are measured by X-ray photoemission and bremsstrahlung isochromat spectroscopy. The diffreences in the spectral shapes of valence bands suggest the importance of the hybridization of U 5f states with T 3d and X 5p states. For all compounds, the unoccupied U 5f state spectra are similar in shape except for small differences in the tailings.",

author = "Takeo Ejima and Yuji Kudo and Shoji Suzuki and Takashi Takahashi and Shigeru Sato and Tadao Kasuya and Toshiro Takabatake and Takehiko Ishii",

year = "1993",

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doi = "10.1016/0921-4526(93)90502-W",

language = "English",

volume = "186-188",

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journal = "Physica B: Condensed Matter",

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TY - JOUR

T1 - XPS and BIS spectra of U3T3X4(T=Ni, Cu and X=Sn, Sb)

AU - Ejima, Takeo

AU - Kudo, Yuji

AU - Suzuki, Shoji

AU - Takahashi, Takashi

AU - Sato, Shigeru

AU - Kasuya, Tadao

AU - Takabatake, Toshiro

AU - Ishii, Takehiko

PY - 1993/5/2

Y1 - 1993/5/2

N2 - Valence state and U 4f core spectra of ternary uranium compounds U3T3X4(T=Ni, Cu and X=Sn, Sb) are measured by X-ray photoemission and bremsstrahlung isochromat spectroscopy. The diffreences in the spectral shapes of valence bands suggest the importance of the hybridization of U 5f states with T 3d and X 5p states. For all compounds, the unoccupied U 5f state spectra are similar in shape except for small differences in the tailings.

AB - Valence state and U 4f core spectra of ternary uranium compounds U3T3X4(T=Ni, Cu and X=Sn, Sb) are measured by X-ray photoemission and bremsstrahlung isochromat spectroscopy. The diffreences in the spectral shapes of valence bands suggest the importance of the hybridization of U 5f states with T 3d and X 5p states. For all compounds, the unoccupied U 5f state spectra are similar in shape except for small differences in the tailings.

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