TY - JOUR
T1 - XAFS study on a pressure-induced superconductor Cs3C60 under high pressure
AU - Fujiki, Satoshi
AU - Kubozono, Yoshihiro
AU - Takabayashi, Yasuhiro
AU - Kashino, Setsuo
AU - Emura, Shuichi
PY - 2001/3/1
Y1 - 2001/3/1
N2 - Cs K-edge XAFS of Cs3C60 which is a pressure-induced superconductor were measured at 21 and 34 kbar by using a diamond anvil cell (DAC) in order to obtain the structural information under high pressure, and to clarify the origin of the pressure-induced superconductivity. The distances and the mean square displacements between the Cs and C atoms are consistent with those determined by X-ray powder diffraction. Consequently, the high-pressure XAFS can give the reliable structural-information on a fullerene superconductor under high pressure. We also show the procedure of the analysis of high-pressure XAFS with DAC in detail.
AB - Cs K-edge XAFS of Cs3C60 which is a pressure-induced superconductor were measured at 21 and 34 kbar by using a diamond anvil cell (DAC) in order to obtain the structural information under high pressure, and to clarify the origin of the pressure-induced superconductivity. The distances and the mean square displacements between the Cs and C atoms are consistent with those determined by X-ray powder diffraction. Consequently, the high-pressure XAFS can give the reliable structural-information on a fullerene superconductor under high pressure. We also show the procedure of the analysis of high-pressure XAFS with DAC in detail.
KW - Cs K-edge XAFS
KW - DAC
KW - High pressure
KW - Pressure-induced superconductor
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U2 - 10.1107/S0909049501000218
DO - 10.1107/S0909049501000218
M3 - Article
C2 - 11512910
AN - SCOPUS:0035289043
SN - 0909-0495
VL - 8
SP - 725
EP - 727
JO - Journal of Synchrotron Radiation
JF - Journal of Synchrotron Radiation
IS - 2
ER -