X-Ray structure analyses of diphosphinidenecyclobutene and its chelate type tetracarbonylmolybdenum(O) complex

Kozo Toyota; Katsuya Tashiro; Masaaki Yoshifuji; Ikuko Miyahara; Atsuhiro Hayashi; Ken Hirotsu

doi:10.1016/0022-328X(92)83340-N

X-Ray structure analyses of diphosphinidenecyclobutene and its chelate type tetracarbonylmolybdenum(O) complex

Kozo Toyota, Katsuya Tashiro, Masaaki Yoshifuji, Ikuko Miyahara, Atsuhiro Hayashi, Ken Hirotsu

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The structure of [(E,E)-3,4-bis(2,4,6-tri-t-butylphenylphosphinidene)-1,2-bis(trimethylsi lyl)cyclobutene]tetracarbonylmolybdenum(O) has been analyzed by X-ray crystallography. The structure of the free ligand, diphosphinidenecyclobutene, has also been analyzed and compared with that of the metal carbonyl complex.

Original language	English
Pages (from-to)	C39-C41
Journal	Journal of Organometallic Chemistry
Volume	431
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(92)83340-N
Publication status	Published - 1992 Jul 7

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "X-Ray structure analyses of diphosphinidenecyclobutene and its chelate type tetracarbonylmolybdenum(O) complex",

abstract = "The structure of [(E,E)-3,4-bis(2,4,6-tri-t-butylphenylphosphinidene)-1,2-bis(trimethylsi lyl)cyclobutene]tetracarbonylmolybdenum(O) has been analyzed by X-ray crystallography. The structure of the free ligand, diphosphinidenecyclobutene, has also been analyzed and compared with that of the metal carbonyl complex.",

author = "Kozo Toyota and Katsuya Tashiro and Masaaki Yoshifuji and Ikuko Miyahara and Atsuhiro Hayashi and Ken Hirotsu",

year = "1992",

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T1 - X-Ray structure analyses of diphosphinidenecyclobutene and its chelate type tetracarbonylmolybdenum(O) complex

AU - Toyota, Kozo

AU - Tashiro, Katsuya

AU - Yoshifuji, Masaaki

AU - Miyahara, Ikuko

AU - Hayashi, Atsuhiro

AU - Hirotsu, Ken

PY - 1992/7/7

Y1 - 1992/7/7

N2 - The structure of [(E,E)-3,4-bis(2,4,6-tri-t-butylphenylphosphinidene)-1,2-bis(trimethylsi lyl)cyclobutene]tetracarbonylmolybdenum(O) has been analyzed by X-ray crystallography. The structure of the free ligand, diphosphinidenecyclobutene, has also been analyzed and compared with that of the metal carbonyl complex.

AB - The structure of [(E,E)-3,4-bis(2,4,6-tri-t-butylphenylphosphinidene)-1,2-bis(trimethylsi lyl)cyclobutene]tetracarbonylmolybdenum(O) has been analyzed by X-ray crystallography. The structure of the free ligand, diphosphinidenecyclobutene, has also been analyzed and compared with that of the metal carbonyl complex.

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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