X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

Yoshihiro Sekine, Masayuki Nihei, Reiji Kumai, Hironori Nakao, Youichi Murakami, Hiroki Oshio

Research output: Contribution to journalArticlepeer-review

21 Citations (Scopus)

Abstract

A cyanide-bridged tetranuclear Fe–Co complex showed electron-transfer-coupled spin transitions induced by X-ray irradiation. Single crystal X-ray diffraction measurements and X-ray absorption spectroscopy revealed that the X-ray-induced phase transition ratio was significantly altered by the selective excitation of the metal ions.

Original languageEnglish
Pages (from-to)4050-4052
Number of pages3
JournalChemical Communications
Volume50
Issue number31
DOIs
Publication statusPublished - 2014 Mar 20
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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