X-Ray Diffuse Scattering in [Pt(en)2][PtCl2(en)2](ClO4)4

Kazuaki Iwasa, Nobuyoshi Wakabayashi, Masamichi Sakai, Noritaka Kuroda, Yuichiro Nishina

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The halogen-bridged transition metal complex [Pt(en)2][PtCl2(en)2](ClO4)4 has a quasi-one dimensional structure with Pt ions forming chains along the b-axis. The valence of the Pt ions can have two possible values, II and IV, and is disordered. Diffuse X-ray scattering was found for wavevectors around (0 2n +1 0). The intensity distribution along the (0 1 0) was very narrow, while that for wavevectors perpendicular to (0 2n +1 0) showed clearly the existence of a short range order between the valence sequences of neighboring chains. A strong correlation has been found between the chain at the origin and one at the second neighbor position along the c-axis. The results were analyzed in terms of interchain interactions.

Original languageEnglish
Pages (from-to)3625-3630
Number of pages6
Journaljournal of the physical society of japan
Volume61
Issue number10
DOIs
Publication statusPublished - 1992 Oct

Keywords

  • halogen bridged compounds
  • interchain interactions
  • mixed valence
  • solitons

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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    Iwasa, K., Wakabayashi, N., Sakai, M., Kuroda, N., & Nishina, Y. (1992). X-Ray Diffuse Scattering in [Pt(en)2][PtCl2(en)2](ClO4)4. journal of the physical society of japan, 61(10), 3625-3630. https://doi.org/10.1143/JPSJ.61.3625