X-Ray Diffuse Scattering in [Pt(en)2][PtCl2(en)2](ClO4)4

Kazuaki Iwasa; Nobuyoshi Wakabayashi; Masamichi Sakai; Noritaka Kuroda; Yuichiro Nishina

doi:10.1143/JPSJ.61.3625

X-Ray Diffuse Scattering in [Pt(en)₂][PtCl₂(en)₂](ClO₄)₄

Kazuaki Iwasa, Nobuyoshi Wakabayashi, Masamichi Sakai, Noritaka Kuroda, Yuichiro Nishina

SCI - Physics

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

The halogen-bridged transition metal complex [Pt(en)2][PtCl2(en)2](ClO4)4 has a quasi-one dimensional structure with Pt ions forming chains along the b-axis. The valence of the Pt ions can have two possible values, II and IV, and is disordered. Diffuse X-ray scattering was found for wavevectors around (0 2n +1 0). The intensity distribution along the (0 1 0) was very narrow, while that for wavevectors perpendicular to (0 2n +1 0) showed clearly the existence of a short range order between the valence sequences of neighboring chains. A strong correlation has been found between the chain at the origin and one at the second neighbor position along the c-axis. The results were analyzed in terms of interchain interactions.

Original language	English
Pages (from-to)	3625-3630
Number of pages	6
Journal	journal of the physical society of japan
Volume	61
Issue number	10
DOIs	https://doi.org/10.1143/JPSJ.61.3625
Publication status	Published - 1992 Oct

Keywords

halogen bridged compounds
interchain interactions
mixed valence
solitons

ASJC Scopus subject areas

Physics and Astronomy(all)

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Iwasa, K., Wakabayashi, N., Sakai, M., Kuroda, N., & Nishina, Y. (1992). X-Ray Diffuse Scattering in [Pt(en)₂][PtCl₂(en)₂](ClO₄)₄. journal of the physical society of japan, 61(10), 3625-3630. https://doi.org/10.1143/JPSJ.61.3625

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title = "X-Ray Diffuse Scattering in [Pt(en)2][PtCl2(en)2](ClO4)4",

abstract = "The halogen-bridged transition metal complex [Pt(en)2][PtCl2(en)2](ClO4)4 has a quasi-one dimensional structure with Pt ions forming chains along the b-axis. The valence of the Pt ions can have two possible values, II and IV, and is disordered. Diffuse X-ray scattering was found for wavevectors around (0 2n +1 0). The intensity distribution along the (0 1 0) was very narrow, while that for wavevectors perpendicular to (0 2n +1 0) showed clearly the existence of a short range order between the valence sequences of neighboring chains. A strong correlation has been found between the chain at the origin and one at the second neighbor position along the c-axis. The results were analyzed in terms of interchain interactions.",

keywords = "halogen bridged compounds, interchain interactions, mixed valence, solitons",

author = "Kazuaki Iwasa and Nobuyoshi Wakabayashi and Masamichi Sakai and Noritaka Kuroda and Yuichiro Nishina",

year = "1992",

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T1 - X-Ray Diffuse Scattering in [Pt(en)2][PtCl2(en)2](ClO4)4

AU - Iwasa, Kazuaki

AU - Wakabayashi, Nobuyoshi

AU - Sakai, Masamichi

AU - Kuroda, Noritaka

AU - Nishina, Yuichiro

PY - 1992/10

Y1 - 1992/10

N2 - The halogen-bridged transition metal complex [Pt(en)2][PtCl2(en)2](ClO4)4 has a quasi-one dimensional structure with Pt ions forming chains along the b-axis. The valence of the Pt ions can have two possible values, II and IV, and is disordered. Diffuse X-ray scattering was found for wavevectors around (0 2n +1 0). The intensity distribution along the (0 1 0) was very narrow, while that for wavevectors perpendicular to (0 2n +1 0) showed clearly the existence of a short range order between the valence sequences of neighboring chains. A strong correlation has been found between the chain at the origin and one at the second neighbor position along the c-axis. The results were analyzed in terms of interchain interactions.

AB - The halogen-bridged transition metal complex [Pt(en)2][PtCl2(en)2](ClO4)4 has a quasi-one dimensional structure with Pt ions forming chains along the b-axis. The valence of the Pt ions can have two possible values, II and IV, and is disordered. Diffuse X-ray scattering was found for wavevectors around (0 2n +1 0). The intensity distribution along the (0 1 0) was very narrow, while that for wavevectors perpendicular to (0 2n +1 0) showed clearly the existence of a short range order between the valence sequences of neighboring chains. A strong correlation has been found between the chain at the origin and one at the second neighbor position along the c-axis. The results were analyzed in terms of interchain interactions.

KW - halogen bridged compounds

KW - interchain interactions

KW - mixed valence

KW - solitons

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