X-RAY DIFFRACTION STUDY OF MIXING STATES IN THE CARBON TETRACHLORIDE SOLUTIONS OF METHANOL AND PENTANE.

Masami Tanaka, Keiko Nishikawa, Kazuyuki Tohji, Tsunetake Fujiyama

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

A simple method has been proposed for estimating the state of mixing in a binary solution directly from the radial distribution function. The method has been applied to the estimation of the size of the cluster or aggregate in a binary solution of methanol and carbon tetrachloride. Pure liquid carbon tetrachloride and a binary solution of pentane and carbon tetrachloride have also been studied as reference systems. The number of methanol molecules which form a cluster in the solution at the volume ratio of 8. 5(CCl//4):1. 5(CH//3OH) has been estimated to be about 18, which is in good agreement with an estimate by light scattering.

Original languageEnglish
Pages (from-to)1273-1278
Number of pages6
JournalBulletin of the Chemical Society of Japan
Volume56
Issue number5
DOIs
Publication statusPublished - 1983 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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