X-ray analysis of a captodative diphosphene, 1-(N-mesityl-9- fluorenylamino)-2-[2,4,6-tris(trifluoromethyl)phenyl]diphosphene

M. Yoshifuji; M. Abe; Kozo Toyota; I. Miyahara; K. Hirotsu

doi:10.1246/bcsj.66.3831

X-ray analysis of a captodative diphosphene, 1-(N-mesityl-9- fluorenylamino)-2-[2,4,6-tris(trifluoromethyl)phenyl]diphosphene

M. Yoshifuji, M. Abe, Kozo Toyota, I. Miyahara, K. Hirotsu

SCI - Chemistry

Research output: Contribution to journal › Comment/debate › peer-review

11 Citations (Scopus)

Abstract

The N-mesityl-9-fluorenylamino group was utilized as an electron-donating new sterically protecting group for stabilizing low coordinate organophosphorus compounds. A push-pull substituent effect on the P-P double bond was demonstrated by the X-ray analysis of a captodative diphosphene, 1- (N-mesityl-9-fluorenylamino)-2-[2,4,6- tris(trifluoromethyl)phenyl]diphosphene.

Original language	English
Pages (from-to)	3831-3833
Number of pages	3
Journal	Bulletin of the Chemical Society of Japan
Volume	66
Issue number	12
DOIs	https://doi.org/10.1246/bcsj.66.3831
Publication status	Published - 1993 Jan 1

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/bcsj.66.3831

Fingerprint Dive into the research topics of 'X-ray analysis of a captodative diphosphene, 1-(N-mesityl-9- fluorenylamino)-2-[2,4,6-tris(trifluoromethyl)phenyl]diphosphene'. Together they form a unique fingerprint.

Cite this

@article{46877b6a73774d48917483344e9e5628,

title = "X-ray analysis of a captodative diphosphene, 1-(N-mesityl-9- fluorenylamino)-2-[2,4,6-tris(trifluoromethyl)phenyl]diphosphene",

abstract = "The N-mesityl-9-fluorenylamino group was utilized as an electron-donating new sterically protecting group for stabilizing low coordinate organophosphorus compounds. A push-pull substituent effect on the P-P double bond was demonstrated by the X-ray analysis of a captodative diphosphene, 1- (N-mesityl-9-fluorenylamino)-2-[2,4,6- tris(trifluoromethyl)phenyl]diphosphene.",

author = "M. Yoshifuji and M. Abe and Kozo Toyota and I. Miyahara and K. Hirotsu",

year = "1993",

month = jan,

day = "1",

doi = "10.1246/bcsj.66.3831",

language = "English",

volume = "66",

pages = "3831--3833",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

publisher = "Chemical Society of Japan",

number = "12",

}

TY - JOUR

T1 - X-ray analysis of a captodative diphosphene, 1-(N-mesityl-9- fluorenylamino)-2-[2,4,6-tris(trifluoromethyl)phenyl]diphosphene

AU - Yoshifuji, M.

AU - Abe, M.

AU - Toyota, Kozo

AU - Miyahara, I.

AU - Hirotsu, K.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - The N-mesityl-9-fluorenylamino group was utilized as an electron-donating new sterically protecting group for stabilizing low coordinate organophosphorus compounds. A push-pull substituent effect on the P-P double bond was demonstrated by the X-ray analysis of a captodative diphosphene, 1- (N-mesityl-9-fluorenylamino)-2-[2,4,6- tris(trifluoromethyl)phenyl]diphosphene.

AB - The N-mesityl-9-fluorenylamino group was utilized as an electron-donating new sterically protecting group for stabilizing low coordinate organophosphorus compounds. A push-pull substituent effect on the P-P double bond was demonstrated by the X-ray analysis of a captodative diphosphene, 1- (N-mesityl-9-fluorenylamino)-2-[2,4,6- tris(trifluoromethyl)phenyl]diphosphene.

UR - http://www.scopus.com/inward/record.url?scp=0027818439&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0027818439&partnerID=8YFLogxK

U2 - 10.1246/bcsj.66.3831

DO - 10.1246/bcsj.66.3831

M3 - Comment/debate

AN - SCOPUS:0027818439

VL - 66

SP - 3831

EP - 3833

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

SN - 0009-2673

IS - 12

ER -