X-ray analysis of a captodative diphosphene, 1-(N-mesityl-9- fluorenylamino)-2-[2,4,6-tris(trifluoromethyl)phenyl]diphosphene

M. Yoshifuji, M. Abe, Kozo Toyota, I. Miyahara, K. Hirotsu

Research output: Contribution to journalComment/debatepeer-review

11 Citations (Scopus)

Abstract

The N-mesityl-9-fluorenylamino group was utilized as an electron-donating new sterically protecting group for stabilizing low coordinate organophosphorus compounds. A push-pull substituent effect on the P-P double bond was demonstrated by the X-ray analysis of a captodative diphosphene, 1- (N-mesityl-9-fluorenylamino)-2-[2,4,6- tris(trifluoromethyl)phenyl]diphosphene.

Original languageEnglish
Pages (from-to)3831-3833
Number of pages3
JournalBulletin of the Chemical Society of Japan
Volume66
Issue number12
DOIs
Publication statusPublished - 1993 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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