Wavelength of luminescence and energy level structure of binuclear copper(I) complex

Tomohiko Ishii, Masahiro Kenmotsu, Kiyoshi Tsuge, Genta Sakane, Yoichi Sasaki, Masahiro Yamashita, Brian Keith Breedlove

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

We investigate the mechanism of strong fluorescence and phosphorescence observed in the binuclear copper complexes by means of a discrete variational (DV)-Xα molecular orbital calculation. Comparing to the energy differences among a occupied and unoccupied molecular orbitals, we can reveal the photon energy of the light of the luminescence in a quantitative way. We also obtained the strong relationship between the observed and the calculated photon energies with according to the conservation of energy principle.

Original languageEnglish
Title of host publicationThe DV-X Molecular-Orbital Calculation Method
PublisherSpringer International Publishing
Pages333-357
Number of pages25
ISBN (Electronic)9783319111858
ISBN (Print)9783319111841
DOIs
Publication statusPublished - 2015 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)
  • Engineering(all)
  • Materials Science(all)

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