Water-vapor-induced reversible switching of electronic states in an MMX-type chain complex with retention of single crystallinity

Hiroaki Iguchi, Shinya Takaishi, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, Shin Ichi Kuroda

Research output: Contribution to journalArticlepeer-review

20 Citations (Scopus)

Abstract

(Figure Presented) Back and forth: Reversible structural change and changes in the physical properties of a quasi-1 D dinuclear Pt complex occurred with dehydration and rehydration. Upon dehydration, the electronic state changed from an alternating charge-polarization and charge-density-wave (ACP + CDW) state to a narrow-gapped CDW state with an increase in the electrical conductivity and molar spin susceptibility at room temperature.

Original languageEnglish
Pages (from-to)552-555
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number3
DOIs
Publication statusPublished - 2010 Jan 12

Keywords

  • Chain structures
  • Electric conductors
  • Phase transitions
  • Platinum
  • Reversible dehydration

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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