TY - JOUR
T1 - Vital role of entropy in photochirogenesis
AU - Inoue, Yoshihisa
AU - Sugahara, Norimitsu
AU - Wada, Takehiko
N1 - Copyright:
Copyright 2018 Elsevier B.V., All rights reserved.
PY - 2001
Y1 - 2001
N2 - The effects of temperature, pressure, solvent, and substrate concentration upon several enantio- and diastereodifferentiating photochemical reactions have been investigated and discussed in detail. These entropy-related external factors, which manipulate the weak electronic and steric interactions in the excited state, dynamically control the stereochemical outcome of asymmetric photochemical reactions, and even switch the product chirality. A global view on the "entropy chemistry" and its potential applications are also discussed.
AB - The effects of temperature, pressure, solvent, and substrate concentration upon several enantio- and diastereodifferentiating photochemical reactions have been investigated and discussed in detail. These entropy-related external factors, which manipulate the weak electronic and steric interactions in the excited state, dynamically control the stereochemical outcome of asymmetric photochemical reactions, and even switch the product chirality. A global view on the "entropy chemistry" and its potential applications are also discussed.
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U2 - 10.1351/pac200173030475
DO - 10.1351/pac200173030475
M3 - Article
AN - SCOPUS:0035743464
VL - 73
SP - 475
EP - 480
JO - Pure and Applied Chemistry
JF - Pure and Applied Chemistry
SN - 0033-4545
IS - 3
ER -