Visualization of nematic liquid crystal director by alignment of π-conjugated polymer nanotubes

Hiromasa Goto, Kohsuke Kawabata

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Furan-based π-conjugated polymer nanotubes were prepared by electrochemical polymerization in nematic liquid crystals (LC) electrolyte resulting in polymer nanotubes aligned with the nematic LC director. Electrochemical polymerization was carried out using the monomer-containing nematic electrolyte by injecting the mixture between sandwich indium tin oxide (ITO)-coated glass electrodes separated by a Teflon sheet. The results show that the optical texture of the nematic LC mixture remains unchanged upon voltage application. The presence of a small amount of water in the nematic electrolyte aids the formation of the tubular structure, and the monomer/water interface is considered to be important in the formation of nanotubes. The insolubility, infusibility, and stiffness of the polymer are considered to prevent reorganization after the polymerization process by effectively locking the order of polymer tubes oriented according to the nematic order.

Original languageEnglish
Pages (from-to)4551-4554
Number of pages4
JournalMacromolecules
Volume41
Issue number13
DOIs
Publication statusPublished - 2008 Jul 8
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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