Visualization of local valence structures in quasi-one-dimensional halogen-bridged complexes [Ni1-xPdx(chxn) 2Br]Br2 by STM

Shinya Takaishi; Hitoshi Miyasaka; Ken Ichi Sugiura; Masahiro Yamashita; Hiroyuki Matsuzaki; Hideo Kishida; Hiroshi Okamoto; Hisaaki Tanaka; Kazuhiro Marumoto; Hiroshi Ito; Shin Ichi Kuroda; Tomohide Takami

doi:10.1002/anie.200453905

Visualization of local valence structures in quasi-one-dimensional halogen-bridged complexes [Ni_1-xPd_x(chxn) ₂Br]Br₂ by STM

Shinya Takaishi, Hitoshi Miyasaka, Ken Ichi Sugiura, Masahiro Yamashita, Hiroyuki Matsuzaki, Hideo Kishida, Hiroshi Okamoto, Hisaaki Tanaka, Kazuhiro Marumoto, Hiroshi Ito, Shin Ichi Kuroda, Tomohide Takami

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

State secrets: Mott-Hubbard and charge-density-wave states have been observed in the quasi-1D bromine-bridged Ni and Pd complexes [M(chxn) ₂Br]Br₂, respectively, using STM (see image for the Ni complex, the arrow denotes the direction of the chain). The spin soliton was also visualized in real space in the Ni-Pd mixed-metal complexes for the first time. chxn: (1R,2R)-diaminocyclohexane.

Original language	English
Pages (from-to)	3171-3175
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	24
DOIs	https://doi.org/10.1002/anie.200453905
Publication status	Published - 2004 Jun 14
Externally published	Yes

Keywords

Bridging ligands
Coordination modes
Mixed-valent compounds
Scanning probe microscopy
Valence structures

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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Takaishi, S., Miyasaka, H., Sugiura, K. I., Yamashita, M., Matsuzaki, H., Kishida, H., Okamoto, H., Tanaka, H., Marumoto, K., Ito, H., Kuroda, S. I., & Takami, T. (2004). Visualization of local valence structures in quasi-one-dimensional halogen-bridged complexes [Ni_1-xPd_x(chxn) ₂Br]Br₂ by STM. Angewandte Chemie - International Edition, 43(24), 3171-3175. https://doi.org/10.1002/anie.200453905

Visualization of local valence structures in quasi-one-dimensional halogen-bridged complexes [Ni_1-xPd_x(chxn) ₂Br]Br₂ by STM. / Takaishi, Shinya ; Miyasaka, Hitoshi; Sugiura, Ken Ichi; Yamashita, Masahiro; Matsuzaki, Hiroyuki; Kishida, Hideo; Okamoto, Hiroshi; Tanaka, Hisaaki; Marumoto, Kazuhiro; Ito, Hiroshi; Kuroda, Shin Ichi; Takami, Tomohide.

In: Angewandte Chemie - International Edition, Vol. 43, No. 24, 14.06.2004, p. 3171-3175.

Research output: Contribution to journal › Article › peer-review

Takaishi, S , Miyasaka, H, Sugiura, KI, Yamashita, M, Matsuzaki, H, Kishida, H, Okamoto, H, Tanaka, H, Marumoto, K, Ito, H, Kuroda, SI & Takami, T 2004, 'Visualization of local valence structures in quasi-one-dimensional halogen-bridged complexes [Ni_1-xPd_x(chxn) ₂Br]Br₂ by STM', Angewandte Chemie - International Edition, vol. 43, no. 24, pp. 3171-3175. https://doi.org/10.1002/anie.200453905

Takaishi, Shinya ; Miyasaka, Hitoshi ; Sugiura, Ken Ichi ; Yamashita, Masahiro ; Matsuzaki, Hiroyuki ; Kishida, Hideo ; Okamoto, Hiroshi ; Tanaka, Hisaaki ; Marumoto, Kazuhiro ; Ito, Hiroshi ; Kuroda, Shin Ichi ; Takami, Tomohide. / Visualization of local valence structures in quasi-one-dimensional halogen-bridged complexes [Ni_1-xPd_x(chxn) ₂Br]Br₂ by STM. In: Angewandte Chemie - International Edition. 2004 ; Vol. 43, No. 24. pp. 3171-3175.

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abstract = "State secrets: Mott-Hubbard and charge-density-wave states have been observed in the quasi-1D bromine-bridged Ni and Pd complexes [M(chxn) 2Br]Br2, respectively, using STM (see image for the Ni complex, the arrow denotes the direction of the chain). The spin soliton was also visualized in real space in the Ni-Pd mixed-metal complexes for the first time. chxn: (1R,2R)-diaminocyclohexane.",

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