Abstract
State secrets: Mott-Hubbard and charge-density-wave states have been observed in the quasi-1D bromine-bridged Ni and Pd complexes [M(chxn) 2Br]Br2, respectively, using STM (see image for the Ni complex, the arrow denotes the direction of the chain). The spin soliton was also visualized in real space in the Ni-Pd mixed-metal complexes for the first time. chxn: (1R,2R)-diaminocyclohexane.
Original language | English |
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Pages (from-to) | 3171-3175 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 43 |
Issue number | 24 |
DOIs | |
Publication status | Published - 2004 Jun 14 |
Externally published | Yes |
Keywords
- Bridging ligands
- Coordination modes
- Mixed-valent compounds
- Scanning probe microscopy
- Valence structures
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)