Vibrationally resolved C and O 1s photoelectron spectra of carbon dioxide

T. Hatamoto, M. Matsumoto, X. J. Liu, K. Ueda, M. Hoshino, K. Nakagawa, T. Tanaka, H. Tanaka, M. Ehara, R. Tamaki, H. Nakatsuji

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

Vibrationally resolved C 1s and O 1s photoelectron spectra of carbon dioxide have been measured with photon energies up to 500 and 700 eV, respectively. Vibrational branching ratios are nearly constant for the C 1s and O 1s photoelectron spectra recorded with the photon energies in the regions 400-500 and 600-700 eV, respectively, where neither shape resonance effect nor photoelectron recoil effect is significant. The information about the potential curves for the C 1s and O 1s ionized states are extracted from these spectra, using the Franck-Condon approximation. The experimental potential curves thus obtained are well reproduced by the present ab initio calculations based on the symmetry adapted cluster-configuration interaction (SAC-CI) method.

Original languageEnglish
Pages (from-to)54-57
Number of pages4
JournalJournal of Electron Spectroscopy and Related Phenomena
Volume155
Issue number1-3
DOIs
Publication statusPublished - 2007 Mar

Keywords

  • Ab initio
  • Carbon dioxide
  • Core-level
  • Photoelectron spectroscopy
  • SAC-CI
  • Synchrotron radiation

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Radiation
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Spectroscopy
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Vibrationally resolved C and O 1s photoelectron spectra of carbon dioxide'. Together they form a unique fingerprint.

Cite this