We present a study of the vibrationally resolved B 1s photoionization cross section of the BF3 molecule. A combination of high-resolution photoelectron spectroscopy measurements and of state-of-the-art calculations shows the evolution of the photon energy dependence of the cross section from a complete trapping of the photoelectron wave (low energies) to oscillations due to intramolecular scattering. These diffraction patterns allow to access structural information of both the neutral molecule and the core -hole species generated upon photoabsoption.
|Journal||Journal of Physics: Conference Series|
|Publication status||Published - 2015 Sep 7|
|Event||29th International Conference on Photonic, Electronic and Atomic Collisions, ICPEAC 2015 - Toledo, Spain|
Duration: 2015 Jul 22 → 2015 Jul 28
ASJC Scopus subject areas
- Physics and Astronomy(all)