Vibrationally autoionizing Rydberg clusters: Spectroscopy and dynamics of pyrazine-Ar and -Xe clusters

Asuka Fujii, Yutaka Kitamura, Naohiko Mikami

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Two color double resonance spectroscopy was used to observe the vibrational autoionization spectra of high Rydberg states of pyrazine Ar and Xe van der Waals clusters. One Rydberg series was observed in bare pyrazine, while two Rydberg series appeared in the spectra of both the clusters. The vibrational autoionization efficiency does not change upon cluster formation, even above the dissociation threshold of the van der Waals bond.

Original languageEnglish
Pages (from-to)8000-8008
Number of pages9
JournalJournal of Chemical Physics
Volume113
Issue number18
DOIs
Publication statusPublished - 2000 Nov 8

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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