Vapour-liquid equilibrium data are reported for four binary systems, carbon dioxide-methyl stearate, carbon dioxide-methyl palmitate, carbon dioxide-methyl myristate and carbon dioxide-methyl oleate, at 313.15, 323.15, 333.15 and 343.15 K. A new recirculating static-type apparatus was developed for these measurements. Fairly good correlation of the data could be obtained except in the critical region by using the Peng-Robinson equation of state and the modified van der Waals mixing rules which required two adjustable binary parameters.
ASJC Scopus subject areas
- Chemical Engineering(all)
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry