TY - JOUR
T1 - Vapor-liquid equilibria for 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) + butane (R600) at various temperatures
AU - Seong, Gimyeong
AU - Lim, Jong Sung
AU - Roh, Hee Kook
AU - Lee, Byung Chul
PY - 2008/1/1
Y1 - 2008/1/1
N2 - Isothermal vapor-liquid equilibrium data for the binary mixture of 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) + butane (R600) were measured at (273.15, 283.15, 293.15, 303.15, 313.15, and 323.15) K, respectively. The experiments were carried out using a continuous circulation-type equilibrium apparatus to measure temperature, pressure, and the compositions of the liquid and vapor phases. The experimental data were correlated with the Peng-Robinson equation of state (PR EOS) using the Wong-Sandier mixing rule. Calculated results showed good agreement with experimental data. It was found that this system has very strong positive azeotropes for all the temperature ranges studied here.
AB - Isothermal vapor-liquid equilibrium data for the binary mixture of 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) + butane (R600) were measured at (273.15, 283.15, 293.15, 303.15, 313.15, and 323.15) K, respectively. The experiments were carried out using a continuous circulation-type equilibrium apparatus to measure temperature, pressure, and the compositions of the liquid and vapor phases. The experimental data were correlated with the Peng-Robinson equation of state (PR EOS) using the Wong-Sandier mixing rule. Calculated results showed good agreement with experimental data. It was found that this system has very strong positive azeotropes for all the temperature ranges studied here.
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U2 - 10.1021/je7004837
DO - 10.1021/je7004837
M3 - Article
AN - SCOPUS:40949123370
VL - 53
SP - 189
EP - 193
JO - Journal of Chemical & Engineering Data
JF - Journal of Chemical & Engineering Data
SN - 0021-9568
IS - 1
ER -