Vapor-liquid equilibria for 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) + butane (R600) at various temperatures

Gimyeong Seong, Jong Sung Lim, Hee Kook Roh, Byung Chul Lee

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Isothermal vapor-liquid equilibrium data for the binary mixture of 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) + butane (R600) were measured at (273.15, 283.15, 293.15, 303.15, 313.15, and 323.15) K, respectively. The experiments were carried out using a continuous circulation-type equilibrium apparatus to measure temperature, pressure, and the compositions of the liquid and vapor phases. The experimental data were correlated with the Peng-Robinson equation of state (PR EOS) using the Wong-Sandier mixing rule. Calculated results showed good agreement with experimental data. It was found that this system has very strong positive azeotropes for all the temperature ranges studied here.

Original languageEnglish
Pages (from-to)189-193
Number of pages5
JournalJournal of Chemical and Engineering Data
Volume53
Issue number1
DOIs
Publication statusPublished - 2008 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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