UV absorption of n-alkyl 1-thio-β-D-glucopyranosides and its utilization in chromatographic separation

Hiroshi Itoh; Fabio Pichierri; Atsushi Kobayashi

doi:10.1016/j.tetlet.2017.08.022

UV absorption of n-alkyl 1-thio-β-D-glucopyranosides and its utilization in chromatographic separation

Hiroshi Itoh, Fabio Pichierri, Atsushi Kobayashi

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The UV absorption of n-alkyl β-D-glucopyranosides has not been utilized so far for their detection which is usually performed by means of the refractive index detector. In this paper, we demonstrate the HPLC separation of several n-alkyl β-D-glucopyranosides with linear gradient by using UV detector and support our findings with time-dependent density functional theory calculations.

Original language	English
Pages (from-to)	3678-3680
Number of pages	3
Journal	Tetrahedron Letters
Volume	58
Issue number	37
DOIs	https://doi.org/10.1016/j.tetlet.2017.08.022
Publication status	Published - 2017 Sep 13

Keywords

HPLC separation
TD-DFT
Thioglucoside
UV absorption

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2017.08.022

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title = "UV absorption of n-alkyl 1-thio-β-D-glucopyranosides and its utilization in chromatographic separation",

abstract = "The UV absorption of n-alkyl β-D-glucopyranosides has not been utilized so far for their detection which is usually performed by means of the refractive index detector. In this paper, we demonstrate the HPLC separation of several n-alkyl β-D-glucopyranosides with linear gradient by using UV detector and support our findings with time-dependent density functional theory calculations.",

keywords = "HPLC separation, TD-DFT, Thioglucoside, UV absorption",

author = "Hiroshi Itoh and Fabio Pichierri and Atsushi Kobayashi",

note = "Funding Information: This research was funded by grants for Strategic Research Foundations at Private Universities 2014–2018 from MEXT of Japan. FP thanks the Department of Applied Chemistry of Tohoku University for financial support. Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd",

year = "2017",

month = sep,

day = "13",

doi = "10.1016/j.tetlet.2017.08.022",

language = "English",

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journal = "Tetrahedron Letters",

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TY - JOUR

T1 - UV absorption of n-alkyl 1-thio-β-D-glucopyranosides and its utilization in chromatographic separation

AU - Itoh, Hiroshi

AU - Pichierri, Fabio

AU - Kobayashi, Atsushi

N1 - Funding Information: This research was funded by grants for Strategic Research Foundations at Private Universities 2014–2018 from MEXT of Japan. FP thanks the Department of Applied Chemistry of Tohoku University for financial support. Publisher Copyright: © 2017 Elsevier Ltd

PY - 2017/9/13

Y1 - 2017/9/13

N2 - The UV absorption of n-alkyl β-D-glucopyranosides has not been utilized so far for their detection which is usually performed by means of the refractive index detector. In this paper, we demonstrate the HPLC separation of several n-alkyl β-D-glucopyranosides with linear gradient by using UV detector and support our findings with time-dependent density functional theory calculations.

AB - The UV absorption of n-alkyl β-D-glucopyranosides has not been utilized so far for their detection which is usually performed by means of the refractive index detector. In this paper, we demonstrate the HPLC separation of several n-alkyl β-D-glucopyranosides with linear gradient by using UV detector and support our findings with time-dependent density functional theory calculations.

KW - HPLC separation

KW - TD-DFT

KW - Thioglucoside

KW - UV absorption

UR - http://www.scopus.com/inward/record.url?scp=85027524386&partnerID=8YFLogxK

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U2 - 10.1016/j.tetlet.2017.08.022

DO - 10.1016/j.tetlet.2017.08.022

M3 - Article

AN - SCOPUS:85027524386

VL - 58

SP - 3678

EP - 3680

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 37

ER -

UV absorption of n-alkyl 1-thio-β-D-glucopyranosides and its utilization in chromatographic separation

Abstract

Keywords

ASJC Scopus subject areas

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