Utilization of chemical and structural characteristics of tetraaza cycloalkane complexes

Tasuku Ito, Masako Kato, Masahiro Yamashita, Haruko Ito

Research output: Contribution to journalArticle

29 Citations (Scopus)


The research investigations aiming at taking advantage of the chemical and structural consequences of ligand macrocyclization are reviewed with regard to the three features as follows: (1) Tetraazacycloalkane complexes which take up carbon dioxide as ROCO2- or R2NCO2-: (2) Correlation between axial and in-plane coordination bond lengths in tetragonal six-coordinate complexes of the trans-MX2N4-type (M=Co3+. Ni2+, and Zn2+)-X-ray structural and ab initio MO studies and (3) Stabilization of high oxidation states of metal ions and its application to chemistry of one-dimensional halogen-bridged M2+-M4+ mixed valence complexes.

Original languageEnglish
Pages (from-to)29-52
Number of pages24
JournalJournal of Coordination Chemistry
Issue number1
Publication statusPublished - 1986 Apr
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Materials Chemistry

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