Unprecedented soliton formation mechanism in quasi-one-dimensional chloro-bridged PtII-PtIV mixed-valence compound, {[Pt(en)2][PtCl2(en)2]}3(CuCl 4)4·12H2O

Masahiro Yamashita, Hidemitsu Aso, Satoshi Matsunaga, Koichi Takizawa, Kazuya Nakata, Chihiro Kachi-Terajima, Fumiyasu Iwahori, Tomohiko Ishii, Hitoshi Miyasaka, Ken Ichi Sugiura, Takuya Kawashima, Kenzi Takai, Noritaka Kuroda, Motoo Shiro, Hideo Kishida, Hiroshi Okamoto, Hiroyuki Takahashi, Hisaaki Tanaka, Kazuhiro Marumoto, Shin Ichi Kuroda

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

A new type of complex consisting of double liner-chain structure {[Pt(en)2][PtCl2(en)2]}3(CuCl 4)4·12H2O was synthesized. High concentration (ca. 200 times larger than the literature) of neutral soliton (PtIII component) formation was found. This unprecedented soliton formation mechanism will be discussed.

Original languageEnglish
Pages (from-to)278-279
Number of pages2
JournalChemistry Letters
Volume32
Issue number3
DOIs
Publication statusPublished - 2003 Mar 5
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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