Unexpected formation of a sterically protected nitrogen pentasulfide ArNS5 (Ar = 2,6-dimesityl-4-methylphenyl) and the X-ray crystallographic analysis

Shigeru Sasaki, Hiroya Hatsushiba, Masaaki Yoshifuji

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

A stable cyclic nitrogen pentasulfide ArNS5 (Ar = 2,6-dimesityl-4-methylphenyl) was unexpectedly obtained by passing the corresponding N-thiosulfinylaniline through a silica gel column and the chair form of the six-membered ring was revealed by X-ray crystallographic analysis.

Original languageEnglish
Pages (from-to)2221-2222
Number of pages2
JournalChemical Communications
Issue number20
DOIs
Publication statusPublished - 1998 Oct 21

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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