Two Stage Implantation Reaction Model in Metal β-Diketonates

K. Yoshihara; A. Miyakawa; M. Homma; T. Sekine

doi:10.1524/ract.1996.73.4.171

Two Stage Implantation Reaction Model in Metal β-Diketonates

K. Yoshihara, A. Miyakawa, M. Homma, T. Sekine

Division of Developmental Research in Education Programs

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1 Citation (Scopus)

Abstract

Recoil implantation reaction is discussed over a wide range 10-10⁵ eV. The reaction model involving a displacement reaction in the low energy region and collision cascade enhancement in the high energy region can be used to reasonably explain the complex yield (Y) and energy (E) relation. The recoil reaction of the implanted *Ru with catcher Fe(dbm)₃ gives *Ru(dbm)₃ where *Ru is ⁹⁷Ru, ¹⁰³Ru. and ¹⁰⁵Ru. For this case the experimental Y - E relation in the low energy region can be fitted by the equation Y = A(E - E_th)ⁿ/[1 + (E - E_th)ⁿ] with threshold (appearance) energy E_th of 154 eV when n is taken as 4. The collision cascade phenomenon in the high energy region is suggested to be strongly correlated with shock wave effects which result in a local Hugoniot state highly compressed and heated in the vicinity of the recoil implanted atom.

Original language	English
Pages (from-to)	171-175
Number of pages	5
Journal	Radiochimica Acta
Volume	73
Issue number	4
DOIs	https://doi.org/10.1524/ract.1996.73.4.171
Publication status	Published - 1996 Jan 1

Keywords

Collision cascade enhancement
Displacement reaction
Implantation reaction
Metal β-diketonate
Two stage model

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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title = "Two Stage Implantation Reaction Model in Metal β-Diketonates",

abstract = "Recoil implantation reaction is discussed over a wide range 10-105 eV. The reaction model involving a displacement reaction in the low energy region and collision cascade enhancement in the high energy region can be used to reasonably explain the complex yield (Y) and energy (E) relation. The recoil reaction of the implanted *Ru with catcher Fe(dbm)3 gives *Ru(dbm)3 where *Ru is 97Ru, 103Ru. and 105Ru. For this case the experimental Y - E relation in the low energy region can be fitted by the equation Y = A(E - Eth)n/[1 + (E - Eth)n] with threshold (appearance) energy Eth of 154 eV when n is taken as 4. The collision cascade phenomenon in the high energy region is suggested to be strongly correlated with shock wave effects which result in a local Hugoniot state highly compressed and heated in the vicinity of the recoil implanted atom.",

keywords = "Collision cascade enhancement, Displacement reaction, Implantation reaction, Metal β-diketonate, Two stage model",

author = "K. Yoshihara and A. Miyakawa and M. Homma and T. Sekine",

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AU - Yoshihara, K.

AU - Miyakawa, A.

AU - Homma, M.

AU - Sekine, T.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Recoil implantation reaction is discussed over a wide range 10-105 eV. The reaction model involving a displacement reaction in the low energy region and collision cascade enhancement in the high energy region can be used to reasonably explain the complex yield (Y) and energy (E) relation. The recoil reaction of the implanted *Ru with catcher Fe(dbm)3 gives *Ru(dbm)3 where *Ru is 97Ru, 103Ru. and 105Ru. For this case the experimental Y - E relation in the low energy region can be fitted by the equation Y = A(E - Eth)n/[1 + (E - Eth)n] with threshold (appearance) energy Eth of 154 eV when n is taken as 4. The collision cascade phenomenon in the high energy region is suggested to be strongly correlated with shock wave effects which result in a local Hugoniot state highly compressed and heated in the vicinity of the recoil implanted atom.

AB - Recoil implantation reaction is discussed over a wide range 10-105 eV. The reaction model involving a displacement reaction in the low energy region and collision cascade enhancement in the high energy region can be used to reasonably explain the complex yield (Y) and energy (E) relation. The recoil reaction of the implanted *Ru with catcher Fe(dbm)3 gives *Ru(dbm)3 where *Ru is 97Ru, 103Ru. and 105Ru. For this case the experimental Y - E relation in the low energy region can be fitted by the equation Y = A(E - Eth)n/[1 + (E - Eth)n] with threshold (appearance) energy Eth of 154 eV when n is taken as 4. The collision cascade phenomenon in the high energy region is suggested to be strongly correlated with shock wave effects which result in a local Hugoniot state highly compressed and heated in the vicinity of the recoil implanted atom.

KW - Collision cascade enhancement

KW - Displacement reaction

KW - Implantation reaction

KW - Metal β-diketonate

KW - Two stage model

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Two Stage Implantation Reaction Model in Metal β-Diketonates

Abstract

Keywords

ASJC Scopus subject areas

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