Two Stage Implantation Reaction Model in Metal β-Diketonates

K. Yoshihara, A. Miyakawa, M. Homma, T. Sekine

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Recoil implantation reaction is discussed over a wide range 10-105 eV. The reaction model involving a displacement reaction in the low energy region and collision cascade enhancement in the high energy region can be used to reasonably explain the complex yield (Y) and energy (E) relation. The recoil reaction of the implanted *Ru with catcher Fe(dbm)3 gives *Ru(dbm)3 where *Ru is 97Ru, 103Ru. and 105Ru. For this case the experimental Y - E relation in the low energy region can be fitted by the equation Y = A(E - Eth)n/[1 + (E - Eth)n] with threshold (appearance) energy Eth of 154 eV when n is taken as 4. The collision cascade phenomenon in the high energy region is suggested to be strongly correlated with shock wave effects which result in a local Hugoniot state highly compressed and heated in the vicinity of the recoil implanted atom.

Original languageEnglish
Pages (from-to)171-175
Number of pages5
JournalRadiochimica Acta
Volume73
Issue number4
DOIs
Publication statusPublished - 1996 Jan 1

Keywords

  • Collision cascade enhancement
  • Displacement reaction
  • Implantation reaction
  • Metal β-diketonate
  • Two stage model

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Two Stage Implantation Reaction Model in Metal β-Diketonates'. Together they form a unique fingerprint.

  • Cite this