Two pentasilahousanes fused together

Akihiro Tsurusaki; Makoto Koganezono; Kyohei Otsuka; Shintaro Ishida; Soichiro Kyushin

doi:10.1002/chem.201403375

Two pentasilahousanes fused together

Akihiro Tsurusaki, Makoto Koganezono, Kyohei Otsuka, Shintaro Ishida, Soichiro Kyushin

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses. Back-to-back silicon houses: The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses.

Original language	English
Pages (from-to)	9263-9266
Number of pages	4
Journal	Chemistry - A European Journal
Volume	20
Issue number	30
DOIs	https://doi.org/10.1002/chem.201403375
Publication status	Published - 2014 Jul 21

Keywords

organosilicon clusters
pentasilahousane
theoretical calculations
trigonal monopyramidal geometry
σ conjugation

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.201403375

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abstract = "The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses. Back-to-back silicon houses: The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses.",

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T1 - Two pentasilahousanes fused together

AU - Tsurusaki, Akihiro

AU - Koganezono, Makoto

AU - Otsuka, Kyohei

AU - Ishida, Shintaro

AU - Kyushin, Soichiro

PY - 2014/7/21

Y1 - 2014/7/21

N2 - The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses. Back-to-back silicon houses: The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses.

AB - The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses. Back-to-back silicon houses: The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses.

KW - organosilicon clusters

KW - pentasilahousane

KW - theoretical calculations

KW - trigonal monopyramidal geometry

KW - σ conjugation

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Two pentasilahousanes fused together

Abstract

Keywords

ASJC Scopus subject areas

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