Abstract
The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses. Back-to-back silicon houses: The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses.
| Original language | English |
|---|---|
| Pages (from-to) | 9263-9266 |
| Number of pages | 4 |
| Journal | Chemistry - A European Journal |
| Volume | 20 |
| Issue number | 30 |
| DOIs | |
| Publication status | Published - 2014 Jul 21 |
Keywords
- organosilicon clusters
- pentasilahousane
- theoretical calculations
- trigonal monopyramidal geometry
- σ conjugation
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
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Cite this
Tsurusaki, A., Koganezono, M., Otsuka, K., Ishida, S., & Kyushin, S. (2014). Two pentasilahousanes fused together. Chemistry - A European Journal, 20(30), 9263-9266. https://doi.org/10.1002/chem.201403375