Two pentasilahousanes fused together

Akihiro Tsurusaki, Makoto Koganezono, Kyohei Otsuka, Shintaro Ishida, Soichiro Kyushin

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses. Back-to-back silicon houses: The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses.

Original languageEnglish
Pages (from-to)9263-9266
Number of pages4
JournalChemistry - A European Journal
Volume20
Issue number30
DOIs
Publication statusPublished - 2014 Jul 21

Keywords

  • organosilicon clusters
  • pentasilahousane
  • theoretical calculations
  • trigonal monopyramidal geometry
  • σ conjugation

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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    Tsurusaki, A., Koganezono, M., Otsuka, K., Ishida, S., & Kyushin, S. (2014). Two pentasilahousanes fused together. Chemistry - A European Journal, 20(30), 9263-9266. https://doi.org/10.1002/chem.201403375