Two-Dimensional Fourier-Transform EPR Nutation Spectroscopy of Spin-Correlated Radical Pairs

Ryuji Hanaishi, Yasunori Ohba, Kimio Akiyama, Seigo Yamauchi, Masamoto Iwaizumi

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The anomalous flip-angle dependence of the Fourier-transform EPR spectrum of photochemically generated spin-correlated radical pair (SCRP) was verified by means of a two-dimensional FT EPR nutation technique. The SCRP signals were partially separated from free-radical signals in the 2D EPR spectrum; SCRP showed additional higher and lower nutation frequencies compared with those of the free radical. Theoretical analyses, including off-resonance effects, are made to explain the experimental results.

Original languageEnglish
Pages (from-to)196-205
Number of pages10
JournalJournal of Magnetic Resonance, Series A
Volume116
Issue number2
DOIs
Publication statusPublished - 1995 Oct

ASJC Scopus subject areas

  • Engineering(all)

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