Two different [1,3]-B shifts in phenalenyl(dipropyl)borane

Oleg L. Tok; Ilya D. Gridnev; Elena M. Korobach; Yuri N. Bubnov

doi:10.1039/a909574h

Two different [1,3]-B shifts in phenalenyl(dipropyl)borane

Oleg L. Tok, Ilya D. Gridnev, Elena M. Korobach, Yuri N. Bubnov

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Both possible [1,3]-B sigmatropic shifts are observed in the title compound; benzylic rearrangement to position 9 is much faster than allylic migration to position 3.

Original language	English
Pages (from-to)	311-312
Number of pages	2
Journal	Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/a909574h
Publication status	Published - 2000 Feb 21
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a909574h

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title = "Two different [1,3]-B shifts in phenalenyl(dipropyl)borane",

abstract = "Both possible [1,3]-B sigmatropic shifts are observed in the title compound; benzylic rearrangement to position 9 is much faster than allylic migration to position 3.",

author = "Tok, {Oleg L.} and Gridnev, {Ilya D.} and Korobach, {Elena M.} and Bubnov, {Yuri N.}",

year = "2000",

month = feb,

day = "21",

doi = "10.1039/a909574h",

language = "English",

pages = "311--312",

journal = "Chemical Communications",

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T1 - Two different [1,3]-B shifts in phenalenyl(dipropyl)borane

AU - Tok, Oleg L.

AU - Gridnev, Ilya D.

AU - Korobach, Elena M.

AU - Bubnov, Yuri N.

PY - 2000/2/21

Y1 - 2000/2/21

N2 - Both possible [1,3]-B sigmatropic shifts are observed in the title compound; benzylic rearrangement to position 9 is much faster than allylic migration to position 3.

AB - Both possible [1,3]-B sigmatropic shifts are observed in the title compound; benzylic rearrangement to position 9 is much faster than allylic migration to position 3.

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U2 - 10.1039/a909574h

DO - 10.1039/a909574h

M3 - Article

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JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 4

ER -

Two different [1,3]-B shifts in phenalenyl(dipropyl)borane

Abstract

ASJC Scopus subject areas

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