Tunneling energy levels of an off-center impurity of the hydroxyl ion in NaCl crystal

T. Nanba; S. Suto; K. Hirota; M. Ikezawa

doi:10.1007/BF01019858

Tunneling energy levels of an off-center impurity of the hydroxyl ion in NaCl crystal

T. Nanba, S. Suto, K. Hirota, M. Ikezawa

Institute for Excellence in Higher Education (IEHE) (organization affiliation only)

Research output: Contribution to journal › Article › peer-review

Abstract

Fine structures of the vibrational spectrum of OH^- in NaCl have been investigated by their dependence on the OH^- concentration, temperature and uniaxial stress. The absorption bands of A and C at 3651. 2 and 3655.2 cm-1 are ascribed to the tunneling motion of the off-center impurity of OH^-. The stress splitting factor of the tunneling levels has been estimated to be B(S11-S12)=0.96±0.10 cm-1/10⁸ dyn cm-2 in the ground state and it is about 1.4 times larger in the vibrational excited state.

Original language	English
Pages (from-to)	1147-1155
Number of pages	9
Journal	International Journal of Infrared and Millimeter Waves
Volume	6
Issue number	11
DOIs	https://doi.org/10.1007/BF01019858
Publication status	Published - 1985 Nov 1

ASJC Scopus subject areas

Radiation
Atomic and Molecular Physics, and Optics
Instrumentation
Condensed Matter Physics
Physics and Astronomy (miscellaneous)
Electrical and Electronic Engineering

Access to Document

10.1007/BF01019858

Cite this

@article{d0d8da70f2be475a9a10b9589ef3f7b8,

title = "Tunneling energy levels of an off-center impurity of the hydroxyl ion in NaCl crystal",

abstract = "Fine structures of the vibrational spectrum of OH- in NaCl have been investigated by their dependence on the OH- concentration, temperature and uniaxial stress. The absorption bands of A and C at 3651. 2 and 3655.2 cm-1 are ascribed to the tunneling motion of the off-center impurity of OH-. The stress splitting factor of the tunneling levels has been estimated to be B(S11-S12)=0.96±0.10 cm-1/108 dyn cm-2 in the ground state and it is about 1.4 times larger in the vibrational excited state.",

author = "T. Nanba and S. Suto and K. Hirota and M. Ikezawa",

year = "1985",

month = nov,

day = "1",

doi = "10.1007/BF01019858",

language = "English",

volume = "6",

pages = "1147--1155",

journal = "Journal of Infrared, Millimeter, and Terahertz Waves",

issn = "1866-6892",

publisher = "Springer New York",

number = "11",

}

TY - JOUR

T1 - Tunneling energy levels of an off-center impurity of the hydroxyl ion in NaCl crystal

AU - Nanba, T.

AU - Suto, S.

AU - Hirota, K.

AU - Ikezawa, M.

PY - 1985/11/1

Y1 - 1985/11/1

N2 - Fine structures of the vibrational spectrum of OH- in NaCl have been investigated by their dependence on the OH- concentration, temperature and uniaxial stress. The absorption bands of A and C at 3651. 2 and 3655.2 cm-1 are ascribed to the tunneling motion of the off-center impurity of OH-. The stress splitting factor of the tunneling levels has been estimated to be B(S11-S12)=0.96±0.10 cm-1/108 dyn cm-2 in the ground state and it is about 1.4 times larger in the vibrational excited state.

AB - Fine structures of the vibrational spectrum of OH- in NaCl have been investigated by their dependence on the OH- concentration, temperature and uniaxial stress. The absorption bands of A and C at 3651. 2 and 3655.2 cm-1 are ascribed to the tunneling motion of the off-center impurity of OH-. The stress splitting factor of the tunneling levels has been estimated to be B(S11-S12)=0.96±0.10 cm-1/108 dyn cm-2 in the ground state and it is about 1.4 times larger in the vibrational excited state.

UR - http://www.scopus.com/inward/record.url?scp=0022162003&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0022162003&partnerID=8YFLogxK

U2 - 10.1007/BF01019858

DO - 10.1007/BF01019858

M3 - Article

AN - SCOPUS:0022162003

SN - 1866-6892

VL - 6

SP - 1147

EP - 1155

JO - Journal of Infrared, Millimeter, and Terahertz Waves

JF - Journal of Infrared, Millimeter, and Terahertz Waves

IS - 11

ER -

Tunneling energy levels of an off-center impurity of the hydroxyl ion in NaCl crystal

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this