Tuning of spin density wave strengths in quasi-one-dimensional mixed-halogen-bridged nickel(III) complexes with strong electron correlation, [NiIII(chxn)2Cl1-xBrx] (NO3)2

Toshio Manabe; Hideo Kishida; Hiroshi Okamoto; Kohei Yokoyama; Sachie Furukawa; Chihiro Kachi-Terajima; Kazuya Nakata; Fumiyasu Iwahori; Hitoshi Miyasaka; Ken ichi Sugiura; Masahiro Yamashita

doi:10.1021/ic025654i

Tuning of spin density wave strengths in quasi-one-dimensional mixed-halogen-bridged nickel(III) complexes with strong electron correlation, [Ni^III(chxn)₂Cl₁-_xBr_x] (NO₃)₂

Toshio Manabe, Hideo Kishida, Hiroshi Okamoto, Kohei Yokoyama, Sachie Furukawa, Chihiro Kachi-Terajima, Kazuya Nakata, Fumiyasu Iwahori, Hitoshi Miyasaka, Ken ichi Sugiura, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

This communication describes the syntheses of the quasi-one-dimensional mixed-halogen-bridged Ni^III complexes with strong electron correlation [Ni(chxn)₂Cl₁-_xBr_x] (NO₃)₂ and the tuning of the spin density wave strengths of these compounds. If the Cl 3p and Br 4p make one band in the compounds, we should observe a single peak in the electronic spectra. As a result, we should observe the single peak from 1.45 to 2.00 eV depending on the mixing ratios of Cl and Br ions. Therefore, the Cl 3p and Br 4p make one band. Then, we have succeeded in tuning the spin density wave strengths of the Ni^III complexes with the strong electron correlation by mixing the bridging halogen ions successively.

Original language	English
Pages (from-to)	4993-4995
Number of pages	3
Journal	Inorganic chemistry
Volume	41
Issue number	20
DOIs	https://doi.org/10.1021/ic025654i
Publication status	Published - 2002 Oct 7
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic025654i

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Manabe, T., Kishida, H., Okamoto, H., Yokoyama, K., Furukawa, S., Kachi-Terajima, C., Nakata, K., Iwahori, F., Miyasaka, H., Sugiura, K. I., & Yamashita, M. (2002). Tuning of spin density wave strengths in quasi-one-dimensional mixed-halogen-bridged nickel(III) complexes with strong electron correlation, [Ni^III(chxn)₂Cl₁-_xBr_x] (NO₃)₂. Inorganic chemistry, 41(20), 4993-4995. https://doi.org/10.1021/ic025654i

Tuning of spin density wave strengths in quasi-one-dimensional mixed-halogen-bridged nickel(III) complexes with strong electron correlation, [Ni^III(chxn)₂Cl₁-_xBr_x] (NO₃)₂. / Manabe, Toshio; Kishida, Hideo; Okamoto, Hiroshi; Yokoyama, Kohei; Furukawa, Sachie; Kachi-Terajima, Chihiro; Nakata, Kazuya; Iwahori, Fumiyasu; Miyasaka, Hitoshi; Sugiura, Ken ichi; Yamashita, Masahiro.

In: Inorganic chemistry, Vol. 41, No. 20, 07.10.2002, p. 4993-4995.

Research output: Contribution to journal › Article › peer-review

Manabe, T, Kishida, H, Okamoto, H, Yokoyama, K, Furukawa, S, Kachi-Terajima, C, Nakata, K, Iwahori, F, Miyasaka, H, Sugiura, KI & Yamashita, M 2002, 'Tuning of spin density wave strengths in quasi-one-dimensional mixed-halogen-bridged nickel(III) complexes with strong electron correlation, [Ni^III(chxn)₂Cl₁-_xBr_x] (NO₃)₂', Inorganic chemistry, vol. 41, no. 20, pp. 4993-4995. https://doi.org/10.1021/ic025654i

Manabe, Toshio ; Kishida, Hideo ; Okamoto, Hiroshi ; Yokoyama, Kohei ; Furukawa, Sachie ; Kachi-Terajima, Chihiro ; Nakata, Kazuya ; Iwahori, Fumiyasu ; Miyasaka, Hitoshi ; Sugiura, Ken ichi ; Yamashita, Masahiro. / Tuning of spin density wave strengths in quasi-one-dimensional mixed-halogen-bridged nickel(III) complexes with strong electron correlation, [Ni^III(chxn)₂Cl₁-_xBr_x] (NO₃)₂. In: Inorganic chemistry. 2002 ; Vol. 41, No. 20. pp. 4993-4995.

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title = "Tuning of spin density wave strengths in quasi-one-dimensional mixed-halogen-bridged nickel(III) complexes with strong electron correlation, [NiIII(chxn)2Cl1-xBrx] (NO3)2",

abstract = "This communication describes the syntheses of the quasi-one-dimensional mixed-halogen-bridged NiIII complexes with strong electron correlation [Ni(chxn)2Cl1-xBrx] (NO3)2 and the tuning of the spin density wave strengths of these compounds. If the Cl 3p and Br 4p make one band in the compounds, we should observe a single peak in the electronic spectra. As a result, we should observe the single peak from 1.45 to 2.00 eV depending on the mixing ratios of Cl and Br ions. Therefore, the Cl 3p and Br 4p make one band. Then, we have succeeded in tuning the spin density wave strengths of the NiIII complexes with the strong electron correlation by mixing the bridging halogen ions successively.",

author = "Toshio Manabe and Hideo Kishida and Hiroshi Okamoto and Kohei Yokoyama and Sachie Furukawa and Chihiro Kachi-Terajima and Kazuya Nakata and Fumiyasu Iwahori and Hitoshi Miyasaka and Sugiura, {Ken ichi} and Masahiro Yamashita",

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AU - Manabe, Toshio

AU - Kishida, Hideo

AU - Okamoto, Hiroshi

AU - Yokoyama, Kohei

AU - Furukawa, Sachie

AU - Kachi-Terajima, Chihiro

AU - Nakata, Kazuya

AU - Iwahori, Fumiyasu

AU - Miyasaka, Hitoshi

AU - Sugiura, Ken ichi

AU - Yamashita, Masahiro

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AB - This communication describes the syntheses of the quasi-one-dimensional mixed-halogen-bridged NiIII complexes with strong electron correlation [Ni(chxn)2Cl1-xBrx] (NO3)2 and the tuning of the spin density wave strengths of these compounds. If the Cl 3p and Br 4p make one band in the compounds, we should observe a single peak in the electronic spectra. As a result, we should observe the single peak from 1.45 to 2.00 eV depending on the mixing ratios of Cl and Br ions. Therefore, the Cl 3p and Br 4p make one band. Then, we have succeeded in tuning the spin density wave strengths of the NiIII complexes with the strong electron correlation by mixing the bridging halogen ions successively.

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