Tuning of spin density wave strength of Ni(III) complexes with strong electron-correlation

T. Ono, M. Yamashita, K. Yokoyama, S. Furukawa, T. Manabe, K. Sugiura, T. Ishii, H. Miyasaka, H. Matsuzaki, H. Kishida, H. Okamoto, K. Marumoto, H. Tanaka, Y. Hasegawa, S. Kuroda, H. Itou

Research output: Contribution to journalArticlepeer-review

Abstract

We have succeeded in synthesizing the NiIII complexes doped by CoIII ions, [Ni1-xCox(chxn)2Br] Br2 (x=0, 0.044, 0.098, 0.118) by using an electrochemical oxidation method. The reflectance spectrum of [Ni1-xCox(chxn) 2]Br2 shows intense charge transfer bands about O.SeV, which are lower than that of [Ni(chxn)2Br]Br2. (1.3eV)

Original languageEnglish
Pages (from-to)357-358
Number of pages2
JournalSynthetic Metals
Volume135-136
DOIs
Publication statusPublished - 2003 Apr 4
Externally publishedYes

Keywords

  • Electrocrystallization
  • Reflection spectroscopy

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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