Tuning of intramolecular π-π overlap mode of tetrathiafulvalene bisannulated macrocycles in the open-shell electronic state

Tomoyuki Akutagawa, Yukako Abe, Tatsuo Hasegawa, Takayoshi Nakamura, Tamotsu Inabe, Christian A. Christensen, Jan Becher

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

Charge-transfer complexes of bis(methylthio)tetrathiafulvalene (DMT-TTF) bisannulated macrocycles with 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ) were prepared. The crystal structural analysis revealed an intramolecular dimer structure with the π-π overlap of DMT-TTF units. The magnitude of intramolecular π-π overlap depends on the ring size of macrocycles.

Original languageEnglish
Pages (from-to)132-133
Number of pages2
JournalChemistry Letters
Issue number2
DOIs
Publication statusPublished - 2000 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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