Tuning of electronic structures of quasi-one-dimensional bromo-bridged PdII-PdIV mixed-valence complexes by substituting counter anions

Hisamitsu Arakawa, Daisuke Kawakami, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Ken Ichi Sugiura, Masahiro Yamashita, Hideo Kishida, Hiroshi Okamoto

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

New quasi-one-dimensional bromo-bridged PdII-PdIV mixed-valence complexes with long chain alkylsufonates [Pd(en) 2][PdBr2(en)](CnH2n+1SO 3)4·2H2O (en = ethylene-diamine, n = 7, 8, 9, and 10) were synthesized. With increasing alkyl-chain length (n) of the counter anions, the PdII⋯PdIV distances decreased, indicating that the oxidation states of the Pd atoms are close to the Pd III state.

Original languageEnglish
Pages (from-to)189-191
Number of pages3
JournalBulletin of the Chemical Society of Japan
Volume80
Issue number1
DOIs
Publication statusPublished - 2007

ASJC Scopus subject areas

  • Chemistry(all)

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