Trigonal bipyramid Ni3Cl3O2 cluster showing the high-spin S = 3 ground state with uniaxial magnetic anisotropy

Yumi Ida, Hiroyuki Nojiri, Takayuki Ishida

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We have prepared a novel nickel(II) trinuclear compound [Ni3(tmen)32-Cl)33-OMe)(μ3-OH)](BPh4)·0.5MeOH·0.5CH2Cl2 (1; tmen: N,N,N′,N′-tetramethylethylenediamine) with a trigonal bipyramid molecular structure, where the basal plane consists of Ni32-Cl)3 atoms. Two known compounds [Ni3(tmen)3X4(OH)]X (X = Cl (2), Br (3)) were also investigated. Magnetic study clarified the ground high-spin (S = 3) state, and the intramolecular exchange coupling parameters were determined as 2J/kB = 18.0 ± 0.2, 27.2 ± 0.2, and 19.6 ± 0.2K for 1, 2, and 3, respectively. Crystallographic analysis clarified the unique geometry of 1. The molecular axes are aligned almost parallel in the crystallographic b axis. Relatively short intermolecular Cl⋯Cl distances (3.725(1) and 3.847(2)Å) are found among linearly arrayed complex ions. A single-crystal magnetic study gave a zero-field-splitting parameter DS=3/kB = -2.2 ± 0.1 K. An intermolecular exchange coupling parameter was determined as 2j/kB = -0.15 ± 0.01K from simulation. A pulsed-field magnetization study at 0.5K for 1 showed a jump around 1.2 T, which is explained in terms of intermolecular interaction. Alternating current magnetic susceptibility measurements revealed the Arrhenius behavior with Ea = 10.1 ± 0.8K at zero bias field. Therefore, the magnetic properties of 1 can be understood as an antiferromagnetic chain made of potential single-molecule magnets.

Original languageEnglish
Pages (from-to)226-236
Number of pages11
JournalBulletin of the Chemical Society of Japan
Issue number2
Publication statusPublished - 2016 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)


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