Triflic imide catalyzed [3+2] cycloaddition of aldimines with α,α-dimethylallylsilane

Naoya Shindoh, Hidetoshi Tokuyama, Yoshiji Takemoto, Kiyosei Takasu

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

Tf2NH-catalyzed [3+2] cycloaddition of N-aryl imines with α,α-dimethylallylsilane to give substituted pyrrolidines is described. We have found the mode of cycloaddition depends upon α-substituents of allylsilanes.

Original languageEnglish
Pages (from-to)187-192
Number of pages6
JournalHeterocycles
Volume77
Issue number1
DOIs
Publication statusPublished - 2009 Jan 1

Keywords

  • Allylsilane
  • Imine
  • Pyrrolidine
  • Triflic Imide
  • [3+2] Cycloaddition

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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