Triflic imide catalyzed [3+2] cycloaddition of aldimines with α,α-dimethylallylsilane

Naoya Shindoh; Hidetoshi Tokuyama; Yoshiji Takemoto; Kiyosei Takasu

doi:10.3987/COM-08-S(F)17

Triflic imide catalyzed [3+2] cycloaddition of aldimines with α,α-dimethylallylsilane

Naoya Shindoh, Hidetoshi Tokuyama, Yoshiji Takemoto, Kiyosei Takasu

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Tf₂NH-catalyzed [3+2] cycloaddition of N-aryl imines with α,α-dimethylallylsilane to give substituted pyrrolidines is described. We have found the mode of cycloaddition depends upon α-substituents of allylsilanes.

Original language	English
Pages (from-to)	187-192
Number of pages	6
Journal	Heterocycles
Volume	77
Issue number	1
DOIs	https://doi.org/10.3987/COM-08-S(F)17
Publication status	Published - 2009 Jan 1

Keywords

Allylsilane
Imine
Pyrrolidine
Triflic Imide
[3+2] Cycloaddition

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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title = "Triflic imide catalyzed [3+2] cycloaddition of aldimines with α,α-dimethylallylsilane",

abstract = "Tf2NH-catalyzed [3+2] cycloaddition of N-aryl imines with α,α-dimethylallylsilane to give substituted pyrrolidines is described. We have found the mode of cycloaddition depends upon α-substituents of allylsilanes.",

keywords = "Allylsilane, Imine, Pyrrolidine, Triflic Imide, [3+2] Cycloaddition",

author = "Naoya Shindoh and Hidetoshi Tokuyama and Yoshiji Takemoto and Kiyosei Takasu",

year = "2009",

month = jan,

day = "1",

doi = "10.3987/COM-08-S(F)17",

language = "English",

volume = "77",

pages = "187--192",

journal = "Heterocycles",

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publisher = "Japan Institute of Heterocyclic Chemistry",

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TY - JOUR

T1 - Triflic imide catalyzed [3+2] cycloaddition of aldimines with α,α-dimethylallylsilane

AU - Shindoh, Naoya

AU - Tokuyama, Hidetoshi

AU - Takemoto, Yoshiji

AU - Takasu, Kiyosei

PY - 2009/1/1

Y1 - 2009/1/1

N2 - Tf2NH-catalyzed [3+2] cycloaddition of N-aryl imines with α,α-dimethylallylsilane to give substituted pyrrolidines is described. We have found the mode of cycloaddition depends upon α-substituents of allylsilanes.

AB - Tf2NH-catalyzed [3+2] cycloaddition of N-aryl imines with α,α-dimethylallylsilane to give substituted pyrrolidines is described. We have found the mode of cycloaddition depends upon α-substituents of allylsilanes.

KW - Allylsilane

KW - Imine

KW - Pyrrolidine

KW - Triflic Imide

KW - [3+2] Cycloaddition

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U2 - 10.3987/COM-08-S(F)17

DO - 10.3987/COM-08-S(F)17

M3 - Article

AN - SCOPUS:65549104163

VL - 77

SP - 187

EP - 192

JO - Heterocycles

JF - Heterocycles

SN - 0385-5414

IS - 1

ER -