Trichloridotris{N-[phenyl(pyridin-2-yl)-methylidene]hydroxylamine- κ 2 N,N′}samarium(III)

Tao Lei, Wenqian Chen, Yanmei Chen, Bin Hu, Yahong Li

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The Sm III ion in the title compound, [SmCl 3(C 12H 10N 2O) 3], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl 3N 6 donor set. The molecular structure is stabilized by three intramolecular O - H⋯Cl hydrogen bonds.

Original languageEnglish
Pages (from-to)m344-m345
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Issue number3
DOIs
Publication statusPublished - 2012 Mar

Keywords

  • R factor = 0.029
  • T = 293 K
  • data-to-parameter ratio = 19.2
  • mean σ(C-C) = 0.004 Å
  • single-crystal X-ray study
  • wR factor = 0.068

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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