Trichloridotris{N-[phenyl(pyridin-2-yl)-methylidene]hydroxylamine- κ 2 N,N′}samarium(III)

Tao Lei; Wenqian Chen; Yanmei Chen; Bin Hu; Yahong Li

doi:10.1107/S1600536812008100

Trichloridotris{N-[phenyl(pyridin-2-yl)-methylidene]hydroxylamine- κ ² N,N′}samarium(III)

Tao Lei, Wenqian Chen, Yanmei Chen, Bin Hu, Yahong Li

Advanced Institute for Materials Research (AIMR)

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The Sm ^III ion in the title compound, [SmCl ₃(C ₁₂H ₁₀N ₂O) ₃], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl ₃N ₆ donor set. The molecular structure is stabilized by three intramolecular O - H⋯Cl hydrogen bonds.

Original language	English
Pages (from-to)	m344-m345
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	3
DOIs	https://doi.org/10.1107/S1600536812008100
Publication status	Published - 2012 Mar

Keywords

R factor = 0.029
T = 293 K
data-to-parameter ratio = 19.2
mean σ(C-C) = 0.004 Å
single-crystal X-ray study
wR factor = 0.068

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536812008100

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title = "Trichloridotris{N-[phenyl(pyridin-2-yl)-methylidene]hydroxylamine- κ 2 N,N′}samarium(III)",

abstract = "The Sm III ion in the title compound, [SmCl 3(C 12H 10N 2O) 3], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl 3N 6 donor set. The molecular structure is stabilized by three intramolecular O - H⋯Cl hydrogen bonds.",

keywords = "R factor = 0.029, T = 293 K, data-to-parameter ratio = 19.2, mean σ(C-C) = 0.004 {\AA}, single-crystal X-ray study, wR factor = 0.068",

author = "Tao Lei and Wenqian Chen and Yanmei Chen and Bin Hu and Yahong Li",

year = "2012",

month = mar,

doi = "10.1107/S1600536812008100",

language = "English",

volume = "68",

pages = "m344--m345",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "3",

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TY - JOUR

T1 - Trichloridotris{N-[phenyl(pyridin-2-yl)-methylidene]hydroxylamine- κ 2 N,N′}samarium(III)

AU - Lei, Tao

AU - Chen, Wenqian

AU - Chen, Yanmei

AU - Hu, Bin

AU - Li, Yahong

PY - 2012/3

Y1 - 2012/3

N2 - The Sm III ion in the title compound, [SmCl 3(C 12H 10N 2O) 3], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl 3N 6 donor set. The molecular structure is stabilized by three intramolecular O - H⋯Cl hydrogen bonds.

AB - The Sm III ion in the title compound, [SmCl 3(C 12H 10N 2O) 3], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl 3N 6 donor set. The molecular structure is stabilized by three intramolecular O - H⋯Cl hydrogen bonds.

KW - R factor = 0.029

KW - T = 293 K

KW - data-to-parameter ratio = 19.2

KW - mean σ(C-C) = 0.004 Å

KW - single-crystal X-ray study

KW - wR factor = 0.068

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U2 - 10.1107/S1600536812008100

DO - 10.1107/S1600536812008100

M3 - Article

C2 - 22412474

AN - SCOPUS:84863230293

VL - 68

SP - m344-m345

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 3

ER -