Translation of the assembling trajectory by preorganisation: A study of the magnetic properties of 1D polymeric unpaired electrons immobilised on a discrete nanoscopic scaffold

Vakayil K. Praveen, Yohei Yamamoto, Takanori Fukushima, Yoshihide Tsunobuchi, Koji Nakabayashi, Shin Ichi Ohkoshi, Kenichi Kato, Masaki Takata, Takuzo Aida

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A nitronyl nitroxide (NN)-appended hexabenzocoronene (HBCNN), when allowed to coassemble with bis(hexafluoroacetylacetonato)cobalt(ii), forms a coaxial nanotubular architecture featuring NN-Co(ii) coordinated copolymer chains immobilised on the outer and inner nanotube surfaces. Upon lowering the temperature, this nanotube has enhanced magnetic susceptibility below 10 K. This journal is

Original languageEnglish
Pages (from-to)1206-1209
Number of pages4
JournalChemical Communications
Volume51
Issue number7
DOIs
Publication statusPublished - 2015 Jan 25
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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