Translation of the assembling trajectory by preorganisation: A study of the magnetic properties of 1D polymeric unpaired electrons immobilised on a discrete nanoscopic scaffold

Vakayil K. Praveen, Yohei Yamamoto, Takanori Fukushima, Yoshihide Tsunobuchi, Koji Nakabayashi, Shin Ichi Ohkoshi, Kenichi Kato, Masaki Takata, Takuzo Aida

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

A nitronyl nitroxide (NN)-appended hexabenzocoronene (HBCNN), when allowed to coassemble with bis(hexafluoroacetylacetonato)cobalt(ii), forms a coaxial nanotubular architecture featuring NN-Co(ii) coordinated copolymer chains immobilised on the outer and inner nanotube surfaces. Upon lowering the temperature, this nanotube has enhanced magnetic susceptibility below 10 K.

Original languageEnglish
Pages (from-to)1206-1209
Number of pages4
JournalChemical Communications
Volume51
Issue number7
DOIs
Publication statusPublished - 2015 Jan 25
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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