Transformation of diols to ketones via intramolecular borrowing hydrogen mechanism

Masazumi Tamura, Takahiro Arai, Yoshinao Nakagawa, Keiichi Tomishige

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Intramolecular borrowing hydrogen methodology composed of dehydrogenation and direct hydrogenolysis is proposed. Rh-MoOx/SiO2 substantiated the methodology and acted as an effective catalyst for transformation of diols to the corresponding ketones in water without external hydrogen sources.

Original languageEnglish
Pages (from-to)1333-1336
Number of pages4
JournalChemistry Letters
Volume46
Issue number9
DOIs
Publication statusPublished - 2017

Keywords

  • Diol
  • Intramolecular borrowing hydrogenation
  • Ketone

ASJC Scopus subject areas

  • Chemistry(all)

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