Abstract
Regioselective cycloaddition of dialkylsilylene upon irradiation at 440 nm converts azulene and guaiazulene to bicyclic [4]dendralene and heptafulvene derivatives, respectively. Significant σ-π interactions in the resulting new silacycles were suggested using UV-vis spectra and theoretical calculations. This journal is
Original language | English |
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Pages (from-to) | 10707-10709 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 51 |
Issue number | 53 |
DOIs | |
Publication status | Published - 2015 Jul 7 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry